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Preface ........................................................................................................................ ...... ix; 1. Reversible Deactivation Radical Polymerization: State-of-the-Art in 2017 ....... 1; Sivaprakash Shanmugam and Krzysztof Matyjaszewski; 2. Mechanistic Insights into Lewis Acid Mediated Sequence- and; Stereo-Control in Radical Copolymerization ...................................................... 41; Nicholas S. Hill, Benjamin B. Noble, and Michelle L. Coote; 3. Time-Resolved Electron Spin Resonance Observations of the Initial Stages; of Conventional and Controlled Radical Polymerization Processes ................. 63; Atsushi Kajiwara; 4. Elements of RAFT Navigation .............................................................................. 77; Joris J Haven, Matthew Hendrikx, Tanja Junkers, Pieter J Leenaers,; Theodora Tsompanoglou, Cyrille Boyer, Jiangtao Xu, Almar Postma, and; Graeme Moad; 5. Reducing the Hydrogen Atom Abstraction Efficiencies of; Benzophenone-Based Photosensitive Alkoxyamines ........................................ 105; Jason C. Morris, Jean-Louis Clement, Yohann Guillaneuf, Steven E. Bottle,; Kathryn Fairfull-Smith, and Didier Gigmes; 6. Catalyzed Radical Termination (CRT) in the Metal-Mediated; Polymerization of Acrylates: Experimental and Computational Studies ...... 135; Thomas G. Ribelli, S. M. Wahidur Rahaman, Krzysztof Matyjaszewski, and; Rinaldo Poli; 7. Electrochemical Procedures To Determine Thermodynamic and Kinetic; Parameters of Atom Transfer Radical Polymerization .................................... 161; Francesca Lorandi, Marco Fantin, Francesco De Bon, Abdirisak A. Isse, and; Armando Gennaro; 8. Insights into the Reactivity of Epoxides as Reducing Agents in; Low-Catalyst-Concentration ATRP Reactions ................................................. 191; David C. McLeod, Kapil Dev Sayala, and Nicolay V. Tsarevsky; 9. Toward Butadiene-ATRP with Group 10 (Ni, Pd, Pt) Metal Complexes ........ 205; Vignesh Vasu, Joon-Sung Kim, Hyun-Seok Yu, William I. Bannerman,; Mark E. Johnson, and Alexandru D. Asandei; 10. Reversible Deactivation Radical Polymerization of Vinyl Chloride ............... 227; Carlos M. R. Abreu, Ana C. Fonseca, Nuno M. P. Rocha, James T. Guthrie,; Armenio C. Serra, and Jorge F. J. Coelho; 11. Photoinduced Metal Free Strategies for Atom Transfer Radical; Polymerization ...................................................................................................... 263; G. Yilmaz, C. Kutahya, A. Allushi, C. Aydogan, S. Aykac, and Y. Yagci; 12. Recent Developments in External Regulation of Reversible Addition; Fragmentation Chain Transfer (RAFT) Polymerization ................................. 273; Sivaprakash Shanmugam, Cyrille Boyer, and Krzysztof Matyjaszewski; 13. How Can Xanthates Control the RAFT Polymerization of Methacrylates? .... 291; Mathias Destarac, Dimitri Matioszek, Xavier Vila, Juliette Ruchmann-Sternchuss,; and Samir Z. Zard; 14. Hydroxyl Radical Activated RAFT Polymerization ......................................... 307; Thomas G. McKenzie, Amin Reyhani, Mitchell D. Nothling, and Greg G. Qiao; 15. Vinyl Ether/Vinyl Ester Copolymerization by Cationic and Radical; Interconvertible Simultaneous Polymerization ................................................. 323; Kotaro Satoh, Yuuma Fujiki, Mineto Uchiyama, and Masami Kamigaito; 16. Catalytic Chain Transfer Polymerization and Reversible Deactivation; Radical Polymerization of Vinyl Acetate Mediated by Cobalt(II); Phenoxy-imine Complexes .................................................................................. 335; Yi-Hao Chen, Hung-Hsun Lu, Jia-Qi Li, and Chi-How Peng; 17. Tailor-Made Poly(vinylamine)s via Thermal or Photochemical; Organometallic Mediated Radical Polymerization ........................................... 349; Pierre Stiernet, Mathilde Drean, Christine Jerome, Patrick Midoux, Philippe Guegan,; Jutta Rieger, and Antoine Debuigne; 18. Alkyl Bromide as Precursor of Initiating Dormant Species in; Organocatalyzed Living Radical Polymerization ............................................. 365; Feifei Li, Longqiang Xiao, and Atsushi Goto; 19. Biocatalytic ATRP ................................................................................................ 379; Jonas Pollard and Nico Bruns; Editors’ Biographies .................................................................................................... 395; Indexes; Author Index ................................................................................................................ 399; Subject Index ................................................................................................................ 401

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