Chemical Thermodynamics：Equilibrium And Nonequilibrium:Reversible And Irreversible Thermodynamics

图书简介

This book enables the reader to learn, in a single volume, equilibrium and nonequilibrium thermodynamics as well as generalized forms of hydrodynamics for linear and nonlinear processes applied to various hydrodynamic flow processes — including chemical oscillation phenomena and pattern formations, shock wave phenomena, sound wave propagations, and Liesegang pattern formation, amongst others. Chemical Thermodynamics introduces advanced undergraduate students and graduate students to the fundamental ideas and notions of the first and second laws of thermodynamics by seamlessly combining equilibrium and nonequilibrium thermodynamics in a unicameral viewpoint based on the first and second law of thermodynamics. Part I of the book discusses equilibrium thermodynamics in historical deference, covering topics generally dealt with in traditional equilibrium thermodynamics. In Part II, the concept of entropy for reversible processes is extended and developed for thermodynamics of irreversible processes by using the concept of calortropy (heat evolution), so that the mathematical theory of macroscopic processes in matter, including a generalized form of hydrodynamics, is ensured to remain consistent with the thermodynamic laws.

Introduction; Part I Equilibrium Thermodynamics: Temperature, Work, and Heat; The First Law of Thermodynamics; The Second Law of Thermodynamics; Carnot Cycle; Carnot’s Theorem; Thermodynamic Temperature; Entropy and Calortropy; Equilibrium Conditions and Thermodynamic Stability; Third Law of Thermodynamics; Thermodynamics of Mixtures and Open Systems; Heterogeneous Equilibria; Thermodynamics of Real Fluids; Canonical Equation of State; Thermodynamics of Real Gas Mixtures; Chemical Equilibria; Thermodynamics of Solutions; Thermodynamics of Surfaces; Electrolyte Solutions; Debye–Hückel Theory of Strong Electrolyte Solutions; Galvanic Cells and Other Classes of Cells; Thermodynamics of Electric and Magnetic Fields; Part II Thermodynamics of Nonequilibrium Processes: Extended Gibbs Relation for Calortropy; Nonequilibrium Effects; Nonequilibrium Effect on Temperature; Nonequilibrium Effect on Pressure; Nonequilibrium Effect on Chemical Potentials; Nonequilibrium Effect on Equilibrium Constants; Linear Irreversible Thermodynamics; Approximations and Assumptions; Viscoelasticity of Fluids; Ultrasonic Wave Propagation and Dispersion in Simple Gases; Ultrasonic Waves in a Rigid Diatomic Gas; Nonlinear Irreversible Processes; Knudsen Problem; Application to Light-Induced Viscous Flow in a Gas; Shock Waves; Oscillatory Structures in Nonlinear Systems; Energy and Matter Dissipation–Calortropy Production; Liesegang and Related Oscillatory Phenomena; Cadmium Sulfide System; Appendices: Second Virial Coefficient of Lennard-Jones Fluids; Analytic Solutions for the Second Virial Coefficient; Local Form of Energy Conservation Law;

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Chemical Thermodynamics：Equilibrium And Nonequilibrium:Reversible And Irreversible Thermodynamics 化学热力学，平衡与非平衡：可逆热力学与不可逆热力学 化学史

Chemical Thermodynamics：Equilibrium And Nonequilibrium:Reversible And Irreversible Thermodynamics

化学热力学，平衡与非平衡：可逆热力学与不可逆热力学
化学史